Nucleophilicities and Carbon Basicities of Pyridines
نویسندگان
چکیده
منابع مشابه
Nucleophilicities and carbon basicities of pyridines.
Rate and equilibrium constants for the reactions of pyridines with donor-substituted benzhydrylium ions have been determined spectrophotometrically. The correlation equation log k(20 degrees C)=s(N+E), in which s and N are nucleophile-specific parameters and E is an electrophile-specific parameter, has been used to determine the nucleophilicity parameters of various pyridines in CH(2)Cl(2) and ...
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ژورنال
عنوان ژورنال: Chemistry - A European Journal
سال: 2006
ISSN: 0947-6539
DOI: 10.1002/chem.200600941